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There is a detailed description of printing modes in JChem for Excel in Printing Structures topic in this guide.
Backstage View Molecule Printing
This option is available only in Microsoft Excel 2010. After selecting the File|Print menu chemical structures are displayed automatically in Backstage View Print Tab if the Backstage View Molecule Printing option was set to TRUE.
Chemical structures are not displayed automatically in the File|Print menu generated in Backstage View Print Tab if this option is set to FALSE (this is the default setting),
but can be displayed by clicking on the Show ChemAxon Structures button. This option is the most advantageous if you would like to print a lot of structures.
It is possible to decide what should be printed out by default or what should be prepared for printing: